Modeling the Polymer-Electrolyte Fuel-Cell Catalyst Layer

Mathematical modelling of the catalyst layer of a polymer electrolyte fuel cell

In this paper, we derive a mathematical model for the cathode catalyst layer of a polymer electrolyte fuel cell. The model explicitly incorporates the restriction placed on oxygen in reaching the reaction sites, capturing the experimentally observed fall in the current density to a limiting value at low cell voltages. Temperature variations and interfacial transfer of O2 between the dissolved a...

Catalyst supports for polymer electrolyte fuel cells.

A major challenge in obtaining long-term durability in fuel cells is to discover catalyst supports that do not corrode, or corrode much more slowly than the current carbon blacks used in today's polymer electrolyte membrane fuel cells. Such materials must be sufficiently stable at low pH (acidic conditions) and high potential, in contact with the polymer membrane and under exposure to hydrogen ...

Proton Conductivity of Graphene-based Nafion® Catalyst Layer for Polymer Electrolyte Membrane Fuel Cell

Modeling and Simulation for Fuel Cell Polymer Electrolyte Membrane

We have established methods to evaluate key properties that are needed to commercialize polyelectrolyte membranes for fuel cell electric vehicles such as water diffusion, gas permeability, and mechanical strength. These methods are based on coarse-graining models. For calculating water diffusion and gas permeability through the membranes, the dissipative particle dynamics–Monte Carlo approach w...

Modeling transport in polymer-electrolyte fuel cells.

In this review, we have examined the different models for polymer-electrolyte fuel cells operating with hydrogen. The major focus has been on transport of the various species within the fuel cell. The different regions of the fuel cell were examined, and their modeling methodologies and equations were elucidated. In particular, the 1-D fuel-cell sandwich was discussed thoroughly because it is t...